S1 - Nunu had best buff/debuff combo + insane base damage on abilities as a support
Alistar was a mid laner who was tanky, had sick sustain from heal and one shot people with combo + lich bane auto
Rumble had too high damage numbers upon release despite people not having him mastered mechanically yet
S2 - Ez was op, because W attack speed buff/debuff wasn't removed from it yet
Jayce one shot people, because he had too much damage with melee form (E was maxed by then for some insane % dmg numbers)
Shen was always strong for the same reason, same goes for back then. He didn't have as good of a kit, but there were far less threatening top laners
S3 - Zed was maxing E back then and he basically put down his W and E'd you twice before the shadow disappeared for free lane win against every match up in the game
Shen - Same as S2
Corki - Because Ez got nerf on his W and Corki got buffed with trinity for worlds, again
S4 - Ali, Zil and Mao were straight up OP, while players got to high enough of an average skill level to handle Lee properly
S5 - Juggernaut + GP reworks and Elise which should've received a major nerf for a long time, yet still didn't
S6 - Nida was OP ap jungler, because of the sick itemization. Syndra was pretty much as strong as she is right now, but with way less opposition and Olaf fit both the tournament META and got enabled by the items in similar fashion to Nida