As I get old here are things I've found make the biggest impact:
good skin care - menopausal/perimenopausal skin is weird. Some people get much drier more sensitive skin and others start to have issues with breakouts/acne. I also find that this is the age when sun damage/damage from other reasons really starts to show. So review your mom's skin care. r/skincareaddiction may offer help depending on any issues she has
good brows - I'm not talking about instagram brows which can be very harsh and aging - I just mean a clean natural look. Many beauty salons offer this service.
3 Hair - I see lots of women my age who have the same haircut they have had for years A good hair cut can make a huge difference. Your mom looks she has hardly any grey - but a good color job can also make a huge difference.