Documents: Remember those brilliant mockups in the Material Design guidelines that Google didn't bother to implement? ^ This app looks exactly like how it was in the guidelines. It's a little low on features currenly but is constantly being updated. Kudos to the dev.
imago: An Imgur client. Alternative would be Open Imgur which is open source.
My source of these excellent apps is this G+ community. Do check it out.
Other brilliant non-Material apps:
Intugame VR: Play your PC games on Google Cardboard. Go through the app description carefully as you need to install some stuff on your PC.
Whatstat ROOT: Some nice stats about all your WhatsApp conversations. Root is required.
Chain Reaction: A fun game to play when with many people in the same room. It's under 200 KB in size. Not responsible for breaking friendships though lol.